Whenever soldering valves to copper play, thicker walls require more heat to work. Sweating copper is all matching, where you search the pipe's outside as well as the "cup" of the installing to be soldered. Flux each with them plus heat the area overall the cup. Then place a torch flame in a spot, applying solder to the opposite side till the heat causes the solder to flow towards it. Solder will flow to heat without exception. But overheating is a possibility, thus eliminate the torch from the play once the solder flows to the heat plus instantly clean it with a wet rag.
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